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Having the camera snap to the fountain upon respawn of your champion is good for people who won't notice they can join the action again, e.g. new players. Unfortunately, the advanced option to disable this camera snap is completely undocumented and hidden deep in the forums, as far as I can tell. I've seen a couple threads asking about it and can no longer find the thread that taught me this option. So, here I am to help!
Find this file:
[...]\Riot Games\League of Legends\Config\game.cfg
Add this line at the end of the "[General]" section.