OSAMA BlN LADEN
I have UFO corki, but i didn't start buying skins till recently so most of my "rare" skins are free ^_^
the only skin I have is sakura karma
Urf the Manatee and Human Ryze
imo the rarest skins in the game are human ryze, black alistar, and rusty blitzcrank.
Festive Maokai would be the most rare skin I own.
Angler Jax and Shamrock Malphite just because they are "legacy"/retired skins
Pax Sivir, Snowbunny nidalee, earnest elf trist, happy elf teemo
For me... eh, it'd have to be Firefighter Tristana.
It's also the first skin I bought, for my favorite champion <3
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