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He should shout "AREYOU NOT ENTERTAINED!"
Edit: Going to add a shout for every single champion.
Edit: Updated with every Champion
Aatrox: The spoils of war rain down upon me!
Ahri : That's what you get for chasing tail!
Akali: Still so many noobs!
Amumu: Everyone around me dies
Anivia: I brought the storm.
Annie: Aw...no more friends...
Ashe - That was cool.
Blitzcrank: Beep Boop!
Brand: YOUR WORLD IS BURNING! AHAHAHAHAH!!!!
Caitlyn: You have the right to remain... dead.
Cassiopeia: I knew my beauty could stop hearts before but this..?(amused chuckle)
Cho'Gath - Tasty!
Corki: Delta Sierra's, Delta Sierra's everywhere...
Darius - Cooldowns? What cooldowns?
Diana: Embrace the Heresy.
Elise: I took them all... to a better place
Ezreal: It's called skill. Look it up.
Evelynn - Look! I'm useful now!
Fiddlesticks - Caw! Caw! Caw!
Fiora: Everybody, poze for ze picture
Fizz: Something was fishy...
Galio: To protect and stop all menaces on my way.
Gangplank: Five men on the dead man's chest!
Garen: I spin AND win!
Gragas: I'll drink to that!
Graves: Another one bites the dust.
Hecarim: Crushed under the hooves of the shadow riders!
Heimerdinger: Raise your Dongers!
Irelia: You better nerf me!
Janna: Did I leave you... breathless?
Jarvan: You see! I am helping!!
Jayce: Stop! Hammertime!
Jax - Ehh no big deal
Jinx: Hehe, everyone died
Katarina: Noxus has no use for weaklings!
Kassadin: My mission has only just begun...
Karma: I'm not so useless after all. (joking tone)
Karthus: My song is complete.
Kayle: I am the law!
Kennen: Now that's what I call stunning.
Kha'Zix: Change truly IS a means to ascension!
Kog'maw: Still so hungry!
LeBlanc - Your health, now you see it. Now you don't.
Lee Sin: Didn't see that one coming!
Leona: Tremble before the power of the sun
Lissandra: Feel the fury of True Ice!
Lucian: Contract, complete.
Lulu - That purple was purple!
Lux - That wasn't too bright of you
Malphite: Rock and Roll!
Malzahar : Let this sacrifice open the doors of this world!
Master Yi: Whoops, I thought you were turrets.
Maokai - I can finally control this torment.
Miss Fortune - Just imagine what I do to pirates!
Mordekaiser: Misery now has company
Morgana - The soil grows in torment
Mundo: Mundo get pentakill when he pleases!
Nami: "Swamped by the waves!"
Nasus : Your cycle has come to an end.
Nautilus: Who's swimming with the fishes now?
Nidalee: Cat got your tongue?
Nocturne - The darkness grows
Nunu: What did I say about making the yeti angry?
Olaf: URGE TO KILL.. satisfied.
Orianna: The ticking has stopped. It was... fun.
Pantheon: THIS IS SPARTA!!
Poppy: Peace was no longer an option.
Quinn: The bird was the word.
Renekton: Sheep to the slaughter!
Rengar: THAT HUNT WAS THRILLING!
Riven - I am redeemed
Rumble - Burn baby burn!
Ryze: Behold the true power of a mage!
Sejuani : Freljord shall know my might!
Shaco: And that, ladies and gentlemen, is how I made an entire team of champions disappear!
Shen: You should have banned me when you had the chance
Shyvana: I told you to get out of the way...
Singed:Told you not to chase me
Sion: They got on my choppa!
Skarner: Nothing more than insects.
Soraka: Oh dear...
Syndra: What can I say? I'm on the ball.
Swain - Quoth the Raven, Nevermore.
Talon - I must have been right on point
Teemo: Captain's Teemo duty is done!
Thresh: All your souls are now mine... but it's not enough!
Tristana: They all fell down and went boom!
Trundle: You're as ugly as youare dead, very.
Tryndamere: I was right...It was a slaughter!
Twisted Fate: Lady Luck just gave me the Jackpot.
Twitch: "And I thought I stink..."
Udyr: Our rage is sated...for now.
Urgot: Feel my pain!
Varus: My work is still not done...
Vayne: The fields of justice have been cleansed.
Veigar - The power has come to me
Vi: What's that? I can't hear you over the sound of me punching you.
Viktor: Frail constructs, youare facing glorious true power!
Vladimir - It has been a bloodbath
Volibear: I suppose you're expecting some unbearable nerf.
Warwick: What a thriller of a fight.
Wukong - That was bananas!
Xerath: See? Only a spark of my power!
Yorick: My.... Quota.....
Xin Zhao: I am as swift as a coursing river!
Yasuo: Justice Demands Retribution!
Zac: I deserve a new suit after that.
Zed: Overwhelmed by shadows!
Ziggs - And boom goes the dynamite!
Zilean: Well about time!
Zyra : The Thorns reign supreme!
If Darius, Jarvan, or Master Yi gets a Penta, Space jam plays in the background.