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I just played a match against a team of jerks (you know what I'm talking about...). I was planning on reporting the instigator of the insults, but when the match was over, the stat screen wouldn't load and after waiting like ten minutes or so, I just clicked "skip waiting for stats." Unfortunately, I don't remember the player's name so I couldn't look him up to report him. I suggest there should be a "Recently Met Players" tab in your profile window, or like something in the Match History tab that allows you to view who you have played against. It could also be useful for people to discuss builds or whatever with teammates/opponents who may have played as a champion they liked, but didn't catch their name in/after game.
EDIT: Sorry, please move to the PVP.net section. Didn't see that section.