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I saw some guy play with a Hextech revolver on mordekaiser as an extremely early item and thought I'd try it out.
I thought the spell vamp and AP added notable survivability to his early/mid game to the boost his ult gets from the AP and the 10% total damage he deals with his abilities. Since I try to fight with creeps around early/mid game in lanes, that 10% total damage really kinda adds up.
Just thought I'd share; it's a fairly cheap, techy, and cool item to buy on the character that is at the very least mildly effective!